catena-Poly[[[aqua­(1,10-phenanthroline-κ2 N,N′)cadmium(II)]-μ-pyridine-2,3-dicarboxyl­ato-κ4 N,O 2:O 3,O 3′] dihydrate]

نویسندگان

  • Ming Li
  • Wuzu Ha
  • Liang Chang
  • Liangjie Yuan
چکیده

The title complex, {[Cd(C(7)H(3)NO(4))(C(12)H(8)N(2))(H(2)O)]·2H(2)O}(n), is a one-dimensional coordination polymer, wherein the Cd atom is seven-coordinated by two 1,10-phenanthroline N atoms, one N and three O atoms from two different pyridine-2,3-dicarboxyl-ate ligands, and one water mol-ecule. It is further extended to a two-dimensional layer structure by hydrogen bonds and π-π stacking inter-actions [centroid-centroid distances of 3.560 (2) and 3.666 (2) Å]. There is a C4 water chain in the structure whose repeat unit contains four water mol-ecules with O⋯O distances in the range 2.748 (3)-2.795 (4) Å. One of the two H atoms of each water of hydration is statistically distributed over two positions with equal occupancy.

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عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008